The end group attached to the permanently hydrophilic block of poly( N, N-dimethylacrylamide) pDMAm is designed as a permanently hydrophobic segment (“sticker”) comprising a long alkyl chain and the 4-aminonaphthalimide fluorophore. ![]() By employing a specifically designed chain-transfer agent, the polymer is functionalized with complementary end groups which are suited for Förster resonance energy transfer (FRET). A nonionic double hydrophilic block copolymer with a long permanently hydrophilic and a small thermoresponsive block is synthesized by reversible addition–fragmentation chain-transfer polymerization (RAFT).
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